The present invention relates to a method to fabricate a multi-layered composition as an electrode material for energy storage. The composition is an electrically conductive multi-layered nanocomposition assembly comprising multilayers having a plurality of materials in each layer. The materials are selected from a group comprising, but not limited to, a conducting polymer, a carbon-based material, a metal oxide/hydroxide, a layered double oxide/hydroxide and mixtures thereof. The developed multilayers consist of carbon-based materials incorporated with pseudocapacitive materials that exhibit fast redox reaction that enhanced the energy storage performance. The multilayers exhibit better conductivity, excellent specific capacitance, high specific energy, high specific power and extraordinary life cycle.